ethylene glycol process flow diagram

Hydrocarbon dew pointing using Joule–Thomson process (Mokhatab et al., 2015). With adequate pressure drop, relatively low temperatures can be produced for hydrocarbon dew point control. Gas-to-gas exchange is very common in NGL recovery processes. The gas cooling effect will cause heavy hydrocarbons to drop out. The spray system is critical in the design of heat exchangers with glycol injection. This free PDF Converter online tool is powered by PDFRock – a PDF Converter powered platform that enables you to convert PDF to Word (PDF to DOC, PDF to DOCX), PDF to PowerPoint (PDF to PPT, PDF to PPTX). The stabilizer is heated with steam or heat medium to produce a Y-grade NGL, which must meet specifications in Table 1.2. Most commercial kinetic inhibitors are high molecular weight polymeric chemicals, which may prevent crystals nucleation or growth during a sufficient delay compared to the residence time in the pipeline. The stabilizer pressure is selected based on NGL liquid composition. Download Ethylene Oxide Ethylene Glycol Process Flow Diagram. Glycol is sprayed into the gas after it leaves the inlet separator and before it undergoes any cooling that can reduce the temperature below the hydrate point. If free water is present, a three-phase separator must be used. By continuing you agree to the use of cookies. In contrast to other types of inhibitors, anti-agglomerators (i.e., growth and slurry additives) inhibit hydrate plugging, rather than hydrate formation. RF-22 (which is cooled in a refrigeration cycle to −40 °F) is able to cool the gas to approximately −40 °F. As stated earlier, the choice between inhibitor alternatives must be based on physical limitations as well as economics. Flow diagram of process employing glycol injection and cooling to dehydrate natural gas. The triethylene glycol dehydration process for offshore gas wells. For example, in a recent project carried out by Baker Petrolite, it was shown that under severe conditions, the required dosage of an anti-agglomerator, unlike thermodynamic and kinetic inhibitors, does not increase as the degree of subcooling increases. Flow diagram of process employing glycol injection and cooling to dehydrate natural gas. For practical purposes, the separator pressure should stay at 10–20% below the critical pressure of the gas mixture. including relevant process flow diagrams. Potential problems include: Incomplete coverage of all heat exchanger tubes with glycol spray, resulting in hydrate formation and plugging in some tubes. However, advances in enhanced glycol dehydration processes, such as the DRIZO system, can solve the problem by production of a BTEX hydrocarbon liquid. The gas leaving the separator from the top contains a small amount of water vapor despite the mist eliminator on top of the separator. Details of the design and operation of glycol injection systems are given by Arnold and Pearce (1961, 1966); Robirds and Martin (1962); and Sheilan (1991). Gas dehydration technology selection. The glycol spray systems are designed to have sufficient pressure drop across the nozzles for good atomization of the injected glycol and even coverage of the exchanger tubes. Process description: •The flow diagram of EO process based on the hydration of EO . The very tough and relatively hard materials based on polyurethane, polyester, or polyamide hard segments are generally regarded as premium products [10–12]. Here both the “wet” and “rich” gas means the gas is rich in water and “dry” and “lean” gas means the gas is lean in water. Liquid from the cold separator is fractionated in a stabilizer or stripper, which removes the methane and lighter components. 1.16). The DRIZO process (under PROSERNAT license) can regenerate TEG to a higher purity than the conventional gas stripping process. Copyright © 2020 Elsevier B.V. or its licensors or contributors. If high propane recovery is required, a deep hydrocarbon dew pointing process (Fluor Process) can be used which can recover over 95% propane (see Section 11.3.3). These factors must be considered in the detailed design of these heat exchangers. If feed gas is available at high pressure or at supercritical pressure, the gas pressure can be used to generate cooling by isenthalpic expansion. Glycol injection is typically required to avoid hydrate formation due to the presence of water in the feed gas. A TEG dehydration unit is lower in CAPEX and OPEX than the molecular sieve unit, especially for offshore installation where plot space is limited. The water-glycol mixture is fed to evaporators where the water is recovered and recycled. If it is desirable to recover ethane, this still is called a demethanizer. Ethylene glycol is generally preferable to diethylene or triethylene glycol for this type of operation because it is less soluble in liquid hydrocarbons, and liquid hydrocarbons are less soluble in ethylene glycol than in the higher glycols. For Y-grade NGL production, the stabilizer operates as a demethanizer, heated with steam or a heat medium. It is desirable to operate the stabilizer pressure as high as possible to minimize gas compression cost. Similarly the “wet” and “rich” glycol means the glycol is rich in water and “dry” and “lean” glycol means the gas is lean in water. As shown in Fig. After passing through the heat exchanger, the gas-glycol mixture is further cooled by expansion through a valve or orifice or by mechanical refrigeration. Many different flow schemes are used for glycol injection systems. Islam, in The Petroleum Engineering Handbook: Sustainable Operations, 2007. Figure 2-5. Therefore, both flow and differential pressure indication must be provided for monitoring spray performance. Report DMCA. Below this temperature, the viscosity of glycol becomes too high for good phase separation. Inadequate mist formation by the injection system, resulting in uneven glycol distribution. This document was uploaded by user and they confirmed that they have the permission to share Therefore, this method of treatment is a cost-effective solution for the control of gas hydrates. The separator is often referred to as the scrubber, the glycol gas absorber as contactor, the still column as stripper, and glycol regenerator as glycol reconcentrator. Hydrocarbon dew point controlling using the J–T process. The cooling causes both water and liquid hydrocarbons to condense. Ethylene Oxide Ethylene Glycol Process Flow Diagram. Huacan Fang, Menglan Duan, in Offshore Operation Facilities, 2014. Geoffrey Holden, in Applied Plastics Engineering Handbook (Second Edition), 2017. These chemicals are called “kinetic inhibitors” and “anti-agglomerant inhibitors”. There is a direct correlation between the glycol flow and the differential pressure across the nozzle. The mixture tends to form emulsions, which are quite stable at low temperature, but separate more rapidly as the temperature increases. Articles made from them are produced by the typical techniques used to process thermoplastics (e.g., injection molding, blow molding, extrusion). They can also be blended with polar polymers such as PVC or used as the hard phase in hard polymer–elastomer combinations [32]. As for the use of silica gel dehydration process, because of its limited short cycle time, it is more suitable for polishing services, such as membrane separator pretreatment, and fuel gas conditioning rather than feed gas to a gas processing plant. The liquid mixture from the primary separator is generally warmed in a fired heater or by heat exchange with the sales gas to reduce liquid viscosities. •The feeds are refind EO and pure H 2 O. This allows for even glycol distribution. We use cookies to help provide and enhance our service and tailor content and ads. The polymers with polyethylene or polypropylene hard segments are lower in cost. Where NGL export pipeline does not exist, the stabilizer can be operated at a lower pressure, to produce a condensate product, typically with 10 psia vapor pressure. In many midstream dew pointing units, J-T units are the most common. Membrane and Twister processes are suitable for small gas plants and offshore installation where space is limited. There are other considerations that may favor the use of molecular sieves. It is possible to recover a small percentage of ethane in a refrigeration plant. Replacing traditional hydrate inhibitors with these new generation of hydrate inhibitors can also lead to substantial cost savings, not only in the reduced cost of the new inhibitor but also in transportation costs and size of the injection, pumping, and storage facilities. 9.20. The refrigeration process is shown as line ABC in the phase diagram. The mixture is then fed to the oil-glycol separator, the oil is removed as product, and the glycol is sent to the regenerator where it is reconcentrated for reuse. including relevant process flow diagrams. The pressure of the cold separator is typically maintained between 600 and 700 psig, depending on the feed gas composition. Uses RF-22 as the refrigerant or working fluid. Molecular sieves are selective and do not appreciably adsorb BTEX components hence avoiding the emission problems in conventional TEG dehydration units. James G. Speight PhD, DSc, in Deep Shale Oil and Gas, 2017. In this process, dried gas is cooled by the cold separator vapor in a gas/gas shell and tube exchanger. Typical flow diagram for glycol injection dehydration system. When the NGL contains excessive amounts of pentane, the pentane hydrocarbons must be removed as a side-draw from the stabilizer column, in order to meet the product's vapor pressure specification. 11.4. The natural gas dehydration process is selected based on the water dew point requirements, as shown in Fig. The J–T letdown operation cools the gas further, producing a liquid condensate in the cold separator. Typically, a packed column located below the reboiler section is used for TEG stripping. By continuing you agree to the use of cookies. it. The mercaptans are concentrated in the regeneration gas, and can be selectively removed using a physical solvent process, such as the DEPG process. Recently, two new types of low-dosage inhibitors have been developed, which will enable the subsea gas transmission pipelines to handle increased gas volumes without additional glycol injection, or extra glycol recovery units. Arthur L. Kohl, Richard B. Nielsen, in Gas Purification (Fifth Edition), 1997. Copyright © 2020 Elsevier B.V. or its licensors or contributors. Inlet gas is cooled to a low enough temperature to condense the desired fraction of LPG and NGL. However, high pressure also increases the bubble point temperature of the stabilizer bottom, which requires a larger reboiler or may also result in thermal degradation. When glycol is sprayed onto the tube sheet and the glycol solution is cooled, the viscosity of the glycol solution increases. The water is absorbed into the glycol, while the liquid hydrocarbons form a separate phase. The chilled gas is reduced in pressure using a Joule–Thomson (J–T) valve. HC liquids are routed to the distillation tower. Figure 7-6. Initially, the process used ethylene glycol as the absorbent but, with the advancement of the technology, glycol dehydration now involves the use of an aqueous solution of a glycol derivative in which the glycol is either diethylene glycol (DEG) or triethylene glycol (TEG) (Table 7.5), which is brought into contact with the water-wet gas stream in a contactor.

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